WebMar 13, 2024 · Herein, for the first time, we have manifested a facile room-temperature DCC-directed transformation of discrete organic imine cage-to-COF film at the liquid … WebJul 19, 2024 · In this work, these untoward effects are minimized by covering Zn electrodes with ultrathin layers of covalent organic frameworks, COFs. These nanoporous and mechanically flexible films form by self-assembly—via the straightforward and scalable dip-coating technique—and permit efficient mass and charge transport while suppressing …
Publications – Dichtel Research Group - Northwestern University
WebMar 23, 2024 · Zhao, Y. et al. A synthetic route for crystals of woven structures, uniform nanocrystals, and thin films of imine covalent organic frameworks. J. Am. Chem. Soc. 139, 13166–13172 (2024). WebSep 1, 2024 · Covalent organic frameworks (COFs) have emerged as a new class of porous materials. In COFs, the basic rigid molecular building blocks are linked through strong covalent bonds to produce two-dimensional and three-dimensional porous frameworks. ... The major hurdles in the scalable fabrication of the CON thin films are … bumper tennis shoes
Functional Covalent Organic Framework Films Based on Surface …
WebJun 1, 2024 · Covalent organic frameworks (COFs) are one of the most rapidly developed porous materials and have exhibited high surface area and uniform pore size distributions as promising materials for the fields of gas adsorption, catalysis, chemical sensing, photoelectricity devices and energy storage. In this review, we summarized the recent … WebCovalent organic framework (COF) films combine the processability of polymers with the porosity and atomic precision of crystalline porous materials, properties that are long … WebFeb 8, 2024 · Here, we report the interfacial polymerization of polyfunctional amine and aldehyde monomers with a Lewis acid catalyst, Sc (OTf)3. Immiscible solutions segregate the catalyst from the monomers, confining polymerization to the solution interface. This method provides large-area, continuous COF films (several cm 2) with a thickness tuned … bumper tennis shoes from the 60\\u0027s