WebJan 1, 2009 · Full size table. Orientational selectivity depends on the size of the pseudostopper: the smaller trimethyl ammonium group gives rise to a preference of 2:1 … WebRemarkably, the same steric bulk of the pseudostopper thus leads to different dethreading rates depending on the stimulus applied. Based on these findings, two redox-switchable …

Precision Molecular Threading/Dethreading - unibo.it

WebAfter identifying a suitable pseudostopper in pseudorotaxane dethreading experiments, this ‘speed bump’ can be integrated into a rotaxane axle to investigate co-conformational … WebAug 22, 2024 · For further amplification of the contraction and stretching motion, tri- and tetra-branched [1](n)rotaxanes (n = 3: compound 2-H; n = 4: compound 3-H) were also synthesized via a similar template-directed click reaction [].2.3 Daisy Chains and Poly[n]daisy Chain-Based Rotaxane Muscles. Recently, significant synthetic effort has … stallone workout routine

Dual-stimuli pseudorotaxane switches under kinetic control

Webguidelines for the rational identification of (pseudo)stopper components that can be useful for designing novel molecular-based devices,machines and materials based on mechanically interlocked molecules and supramolecular counterparts. Results and Discussion Design and synthesis of the components Theinvestigated compounds are … WebThe fact that the threading barrier at the pseudostopper end lies between those at the E- and Z-azobenzene ends enables the directionality at the basis of the pump operation. … Webguidelines for the rational identification of (pseudo)stopper components that can be useful for designing novel molecular-based devices,machines and materials based on … stallone wrote rocky